| Statistic | Value | Details |
| Biggest win by Sydney FC | 4 goals | 30/04/2023 Western United 0-4 Sydney FC (Grand Final) |
| Biggest win by Western United | 2 goals | 11/01/2023 Western United 2-0 Sydney FC |
| Most goals scored by Sydney FC against Western United | 4 goals | 30/04/2023 Western United 0-4 Sydney FC (Grand Final) |
| Most goals scored by Western United against Sydney FC | 2 goals | 11/01/2023 Western United 2-0 Sydney FC |
| 8/12/2024 Western United 2-1 Sydney FC | ||
| 9/02/2025 Sydney FC 1-2 Western United | ||
| Red cards | Natalie Tobin | 5/03/2023 Sydney FC 3-0 Western United |
| Hattricks scored in this fixture | None | N/A |
| Most goals scored in this fixture | 1. 3 goals | Hannah Keane |
| Cortnee Vine | ||
| 3. 2 goals | Rachel Lowe | |
| Kahli Mary Johnson | ||
| Princess Ibini | ||
| Madison Haley |
| Season | Date | Match Type | Sydney FC wins | Draws | Western United wins |
| 2022/23 | 11/01/2023 | League | Western United 2-0 Sydney FC | ||
| 2022/23 | 5/03/2023 | League | Sydney FC 3-0 Western United | ||
| 2022/23 | 16/04/2023 | Finals | Sydney FC 0-1 Western United | ||
| 2022/23 | 30/04/2023 | Grand Final | Western United 0-4 Sydney FC | ||
| 2023/24 | 14/01/2024 | League | Western United 0-1 Sydney FC | ||
| 2023/24 | 9/03/2024 | League | Sydney FC 3-1 Western United | ||
| 2024/25 | 8/12/2024 | League | Western United 2-1 Sydney FC | ||
| 2024/25 | 9/02/2025 | League | Sydney FC 1-2 Western United |